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Orientation of perylene derivatives on semiconductor surfaces
Orientation of perylene derivatives on semiconductor surfaces

... The incident synchrotron light is linear polarized with the electric field vector lying in the plane of incidence. For an angle of incidence of 08 only broad features above 280 eV photon energy are observed. When changing the angle of incidence to 38 and 708, however, sharp structures below 280 eV p ...
Sodium D Line Data
Sodium D Line Data

An Overview of Organic Reactions
An Overview of Organic Reactions

... In a clock the hands move but the mechanism behind the face is what causes the movement In an organic reaction, we see the transformation that has occurred. The mechanism describes the steps behind the changes that we can observe Reactions occur in defined steps that lead from reactant to product ...
Transition form factor of the hydrogen Rydberg atom
Transition form factor of the hydrogen Rydberg atom

Large Gate Modulation in the Current of a Room Temperature
Large Gate Modulation in the Current of a Room Temperature

Bond
Bond

... Molecules composed of covalently bonded atoms may also exhibit polar or nonpolar properties. For the molecule to be polar, it must, of course have polar bonds. But the key factor in determining the polarity of a molecule is its shape, or geometry. If the polar bonds are arranged symmetrically around ...
On the Theory of Intramolecular Energy Transfer
On the Theory of Intramolecular Energy Transfer

Low-Energy Excitations and Ground State Selection in Quantum
Low-Energy Excitations and Ground State Selection in Quantum

... performed heat capacity measurements in the range 24 mK to 1 K, the results of this are shown in Fig. 3(c). Rather than a sharp peak indicative of a phase transition, the heat capacity exhibits a broad peak at T ∼ 63 mK. The entropy change per Yb3+ ion is calculated to be 1.4 J/K ∼ R/4 ln(2); the ca ...
Pdf
Pdf

... color goes up and as much as delocalization of the electrons happen, and that is related to the various functional or auxochromes that are connected to these aromatic rings. Some of the most important red dyes are based on anthraquinone structure. They are obtained both from plants and insects. Thes ...
Models relevant to excess heat production in fleischmann- pons experiments Please share
Models relevant to excess heat production in fleischmann- pons experiments Please share

metal
metal

Alkali D Line Data
Alkali D Line Data

... term. This interaction splits the sublevels such that sublevels with the same value of |mF | remain degenerate. An expression for the hyperfine Stark shift, assuming a weak enough field that the shift is small compared to the hyperfine splittings, is [27] ∆E|J I F ...
Spontaneous Emission Spectrum in Double Quantum Dot Devices
Spontaneous Emission Spectrum in Double Quantum Dot Devices

... to elastic tunneling and has a Lorentzian line shape Iel(«) 5 Iel,maxv2/(v2 1 «2) (11). The full width at half maximum, 2v, can be tuned by the central gate voltage VGC roughly from 4 to 20 meV. From measurements of Iel(«) at positive and negative VSD, it is possible to extract values for the tunnel ...
Vacuum Ultraviolet Spectroscopy and Photochemistry of Zinc
Vacuum Ultraviolet Spectroscopy and Photochemistry of Zinc

Time of flight-photoemission electron microscope for ultrahigh
Time of flight-photoemission electron microscope for ultrahigh

... located than the spectra obtained with Hg lamp excitation. Therefore the contrast change becomes weaker in this case as compared to the image series obtained with the IEF mode. Furthermore, it is interesting to note that we observe some bright spots in the PEEM images under 400 nm/60 ps laser excita ...
Evidence from the Absorption and Emission Spectra
Evidence from the Absorption and Emission Spectra

Proton tunneling in hydrogen bonds and its possible implications in
Proton tunneling in hydrogen bonds and its possible implications in

... or the hydrophobic, geometric and electronic characteristics of the enzyme primarily determined by trivial quantum effects responsible for bonding. Effects such as quantum superposition, tunneling, and entanglement are usually thought to play no significant role in the catalytic activity of the mole ...
Laser-active medium
Laser-active medium

... Spectroscopy 2: Electronic Transitions CHAPTER 14 ...
Introduction to Single Molecular Magnet
Introduction to Single Molecular Magnet

Quantum Theory of Chiral Interactions in Cholesteric Liquid Crystals
Quantum Theory of Chiral Interactions in Cholesteric Liquid Crystals

... the rather complex interactions between mesogens and the orientational correlations they induce. If there are chiral mesogens, there are chiral interactions, and h is nonzero; otherwise, h is zero. One typically identifies three types of interactions between molecules @6#: ~1! long-range attractive ...
Electron Ground States in a Few-Electron quantum Dot.
Electron Ground States in a Few-Electron quantum Dot.

... obtain a current flow. Subsequently, all experiments then have to be performed far out of equilibrium, which limits the energy resolution. From these materials two-terminal [8] as well as three-terminal devices [9] have been fabricated. These early three-terminal devices could only be studied in the ...
Making Sense of Boiling Points and Melting Points
Making Sense of Boiling Points and Melting Points

... Dipole-induced dipole interaction refers to a molecule with a permanent dipole (like water), inducing a dipole in an otherwise non-polar molecule (like bromine), as shown in Figure 6. The extent of induction of dipole depends on the polarisability of the non-polar molecule. Polarisability is a measu ...
Triple resonance for a three-level system of a chiral molecule
Triple resonance for a three-level system of a chiral molecule

... a long time. We may wonder how we can understand the rotational spectra of C1 chiral molecules. This is the start of the present research; I suspected that this puzzle was closely related to Hund’s paradox. I keep in mind mainly pure rotational spectroscopy of molecules such as microwave spectroscop ...
anal chem II / IR spectrometry
anal chem II / IR spectrometry

Imaging of single-chromophore molecules in aqueous
Imaging of single-chromophore molecules in aqueous

... wide-field imaging of single rhodamine dye molecules evaporated from droplets onto a fused silica substrate using a Hamamatsu intensified silicon-intensified-target (ISIT) camera with single-photon counting capability.11 Funatsu, et al., reported detection of macromolecules or small molecules in sol ...
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Franck–Condon principle



The Franck–Condon principle is a rule in spectroscopy and quantum chemistry that explains the intensity of vibronic transitions. Vibronic transitions are the simultaneous changes in electronic and vibrational energy levels of a molecule due to the absorption or emission of a photon of the appropriate energy. The principle states that during an electronic transition, a change from one vibrational energy level to another will be more likely to happen if the two vibrational wave functions overlap more significantly.
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