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Absorption and fluorescence spectra of poly
Absorption and fluorescence spectra of poly

... interchain dimer formation is expected to dominate. The PET, with a weight-average molecular weight equal to 75000 (based on its intrinsic viscosity"4 ), will have a radius of gyration (RG) equal to 23 nm under theta conditions 1 5 . This corresponds to a chain overlap concentration of roughly 0.01 ...
SECOND DRAFT FOR
SECOND DRAFT FOR

2. Nuclear models and stability
2. Nuclear models and stability

Fano resonances in the excitation spectra of semiconductor
Fano resonances in the excitation spectra of semiconductor

... light-hole exciton of 0.85 meV, and the occurrence of well-resolved excited states of the light- and heavy-hole excitons. In the inset of Fig. 1, peak 1 is the ground state of the light-hole exciton. The peaks labeled 2 and 4 are assigned to the n =2 excited states of the heavy- and light-hole excit ...
Jahn−Teller Distortion in the Phosphorescent Excited State of Three
Jahn−Teller Distortion in the Phosphorescent Excited State of Three

Postprint
Postprint

... it is of interest to compare the two approaches. Indeed, as we shall show below, a link can be found when reducing the laser intensity of the streaking field so that one reaches the domain of applicability of the recently developed Phase-Retrieval by Omega Oscillation Filtering (PROOF) scheme, [20]. ...
On the physical interpretation of torsion
On the physical interpretation of torsion

... of the coefficient of the operator at the bottom of the well, while C 0 12C 3 gives the value for that same coefficient at the top of the barrier. ~We note in passing that an alternative expansion of the form @ C 80 1C 83 cos 3g# @quadratic operator# gives a value of C 80 1C 83 at the bottom of the ...
Imaging resonances in low-energy NO-He inelastic collisions REPORTS
Imaging resonances in low-energy NO-He inelastic collisions REPORTS

... partial waves depends on the de Broglie wavelengths of the particles; observable quantities such as scattering cross sections therefore necessarily represent the quantum mechanical superposition of many partial waves (2). Classically, this can be compared with the unavoidable averaging over all poss ...
Journal of the American Chemical Society, 120(15)
Journal of the American Chemical Society, 120(15)

... Abstract: In contrast to porphyrins and chlorins, the direct metalation of bacteriochlorins is difficult. Nevertheless, Cu2+ and Zn2+ can be introduced into bacteriopheophytin in acetic acid, whereas Cd2+ can be inserted in dimethylformamide. The former reactions depend on the substituents of the is ...
Regular/irregular phase space structure of HCN/HNC
Regular/irregular phase space structure of HCN/HNC

cond-mat/0406008 PDF
cond-mat/0406008 PDF

... on its distribution. The change in the critical exponent from its classical counterpart can be traced to the fact that as the Fermi energy, or concentration of SC links, change, the transmission amplitude through the quantum insulator is modified, as the bottle-neck link changes. We also note that r ...
"Global Analytical Potential Energy Surfaces for High
"Global Analytical Potential Energy Surfaces for High

... Benchmark ab initio calculations of molecular spectroscopic states exist for H2 , for instance. Highly accurate calculations of the electronic ground-state (Wolniewicz 1993) and excited state potential energy functions (Yu and Dressler 1994) allowed these authors to obtain wavenumbers of rovibronic ...
Criticality at the Haldane-insulator charge-density
Criticality at the Haldane-insulator charge-density

... and a finite energy gap. The Landau symmetry breaking states belong to this class. However, there are more interesting SPT states that do not break any symmetry. For example, in higher dimensions, the Kane-Mele band insulator [5, 6] is a topological state protected by U (1) and time-reversal symmetr ...
Spin-Orbit-Mediated Anisotropic Spin Interaction in Interacting Electron Systems
Spin-Orbit-Mediated Anisotropic Spin Interaction in Interacting Electron Systems

Interaction energy surfaces of small hydrocarbon molecules
Interaction energy surfaces of small hydrocarbon molecules

... configurations of dimers involving slightly larger hydrocarbons. The completed work provides interaction energy surfaces for all combinations of dimer pairs involving ethane, propane, isobutane, and neopentane and thus contains information of all chemical groups found in acyclic alkanes. The stronge ...
Optical absorption cross section of quantum dots
Optical absorption cross section of quantum dots

... It is enlightening to compare the experimental value of the spectrally integrated cross section with the value given by equation (4). The simplest situation is where the overlap integral of the envelope functions F(r) is unity, however a further question arises regarding the value to be used for the ...
Long-range Rydberg-Rydberg interactions in calcium, strontium and
Long-range Rydberg-Rydberg interactions in calcium, strontium and

The Tunneling Time of an Electron
The Tunneling Time of an Electron

Few-Particle Effects in Semiconductor Quantum Dots: Spectrum Calculations on
Few-Particle Effects in Semiconductor Quantum Dots: Spectrum Calculations on

PHZ 7427 SOLID STATE II: Electron-electron interaction and the
PHZ 7427 SOLID STATE II: Electron-electron interaction and the

... Let the total electrostatic potential acting on an electron be φ = φext + φind , where φext is the potential of external charges and φind is that of induced charges. Correspondingly, the potential energy v = −eφ = −eφext − eφind . Because we are doing the linear-response theory, the form of the exte ...
the PDF - JILA Science - University of Colorado Boulder
the PDF - JILA Science - University of Colorado Boulder

Optical control of the spin state of two Mn atoms... L. Besombes, C. L. Cao, S. Jamet,
Optical control of the spin state of two Mn atoms... L. Besombes, C. L. Cao, S. Jamet,

Energy Transfer to Phonons in Atom and Molecule Collisions with
Energy Transfer to Phonons in Atom and Molecule Collisions with

Chiral specific electron vortex beam spectroscopy
Chiral specific electron vortex beam spectroscopy

... are currently the focus of much interest following the prediction by Bliokh et al. [1] and their experimental realization in a number of laboratories, using various techniques [2–7]. This area has recently emerged after much fruitful research has been carried out on optical vortices (OVs) over the l ...
Module P11.4 Quantum physics of solids
Module P11.4 Quantum physics of solids

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Franck–Condon principle



The Franck–Condon principle is a rule in spectroscopy and quantum chemistry that explains the intensity of vibronic transitions. Vibronic transitions are the simultaneous changes in electronic and vibrational energy levels of a molecule due to the absorption or emission of a photon of the appropriate energy. The principle states that during an electronic transition, a change from one vibrational energy level to another will be more likely to happen if the two vibrational wave functions overlap more significantly.
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