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physical setting chemistry
physical setting chemistry

... Record the number of your choice for each Part A and Part B–1 multiple-choice question on your separate answer sheet. Write your answers to the Part B–2 and Part C questions in your answer booklet. All work should be written in pen, except for graphs and drawings, which should be done in pencil. You ...
Optical spectroscopy and electronic structure of the face-centered icosahedral quasicrystals Zn- R
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... agreement with results of Hall effect measurements on Zn-MgY,15 which indicate that the effective electron concentration is very low, neff = 2.3 × 1021 cm−3 , as compared to the valence electron concentration n = 1.17 × 1023 cm−3 (Table I). The Zn-Mg-R energy spectrum scheme presented in Fig. 6 allo ...
Chemistry
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Fundamental Disagreement of Wave Mechanics with Relativity
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Quantum Turbulence - University of Warwick

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... matrix solution that has already been placed onto the target. The solution is dried and allowed to crystallize so that it is comprised of microcrystals of a matrix into which the analytes are embedded. The target is placed, through a vacuum interlock, into the path of the laser beam in the ion sourc ...
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... In the second model the effect of adjacent lattice atoms on fusion is examined with a 1-½ dimensional model. First a quantum barrier model is formulated using the transfer matrix approach. Then additional barriers are introduced in the form of adjacent lattice atoms. Initial results show possible re ...
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... we ignore the phase accumulation in each path; thus we follow populations instead of amplitudes. This is a very good approximation for SFI once the levels from n⫺1 and n⫹1 start to cross, since there are a very large number of paths that lead to ionization at field F, with nearly randomly varying ph ...
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Wave equation with energy-dependent potentials for confined systems

... In the present work, we follow the strategy of directly introducing energy-dependent potentials in the wave equation. It has the advantage of keeping these terms in a compact way. The result is a class of pseudo-Hermitian Hamiltonians, which could be used to describe nonlinear situations. The use of ...
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... temperature was lowered to 485 ° C before the growth of the In0.15Ga0.85As QW and the QD layer. The lower In0.15Ga0.85As QW was grown immediately before the QDs at a growth rate of 0.67 nm/s. The InAs layer was grown at a V/III ratio of 13, with a nominal thickness of 1.8 ML and a growth rate of 0.1 ...
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... Bohr's model correctly predicted values for hydrogen's spectrum, but was unable to predict other elements' spectra. Bohr's assumptions include quantized energy levels, atom emits or absorbs radiation only when it changes states, and angular momentum is quantized. 25. Gas-Discharge Tubes Describe how ...
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... molecule with its neighbours. In contrast, light emitted from rarefied gases heated in a flame, or excited electrically in a glow tube such as the familiar neon sign or mercury vapour light has only certain discrete wavelengths. The spectrum appears as a series of bright lines. In such gases, the av ...
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... The principal quantum number n can be any integer ≥1. The larger the value of n, the more energy the orbital has. Energies are defined as being negative. (An electron would have E = 0 when it just escapes the atom.) The larger the value of n, the larger the orbital. As n gets larger, the amount of e ...
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X-ray photoelectron spectroscopy



X-ray photoelectron spectroscopy (XPS) is a surface-sensitive quantitative spectroscopic technique that measures the elemental composition at the parts per thousand range, empirical formula, chemical state and electronic state of the elements that exist within a material. XPS spectra are obtained by irradiating a material with a beam of X-rays while simultaneously measuring the kinetic energy and number of electrons that escape from the top 0 to 10 nm of the material being analyzed. XPS requires high vacuum (P ~ 10−8 millibar) or ultra-high vacuum (UHV; P < 10−9 millibar) conditions, although a current area of development is ambient-pressure XPS, in which samples are analyzed at pressures of a few tens of millibar.XPS is a surface chemical analysis technique that can be used to analyze the surface chemistry of a material in its as-received state, or after some treatment, for example: fracturing, cutting or scraping in air or UHV to expose the bulk chemistry, ion beam etching to clean off some or all of the surface contamination (with mild ion etching) or to intentionally expose deeper layers of the sample (with more extensive ion etching) in depth-profiling XPS, exposure to heat to study the changes due to heating, exposure to reactive gases or solutions, exposure to ion beam implant, exposure to ultraviolet light.XPS is also known as ESCA (Electron Spectroscopy for Chemical Analysis), an abbreviation introduced by Kai Siegbahn's research group to emphasize the chemical (rather than merely elemental) information that the technique provides.In principle XPS detects all elements. In practice, using typical laboratory-scale X-ray sources, XPS detects all elements with an atomic number (Z) of 3 (lithium) and above. It cannot easily detect hydrogen (Z = 1) or helium (Z = 2).Detection limits for most of the elements (on a modern instrument) are in the parts per thousand range. Detection limits of parts per million (ppm) are possible, but require special conditions: concentration at top surface or very long collection time (overnight).XPS is routinely used to analyze inorganic compounds, metal alloys, semiconductors, polymers, elements, catalysts, glasses, ceramics, paints, papers, inks, woods, plant parts, make-up, teeth, bones, medical implants, bio-materials, viscous oils, glues, ion-modified materials and many others.XPS is less routinely used to analyze the hydrated forms of some of the above materials by freezing the samples in their hydrated state in an ultra pure environment, and allowing or causing multilayers of ice to sublime away prior to analysis. Such hydrated XPS analysis allows hydrated sample structures, which may be different from vacuum-dehydrated sample structures, to be studied in their more relevant as-used hydrated structure. Many bio-materials such as hydrogels are examples of such samples.
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