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Post Print Electronic structure and chemical bonding in Ti2AlC
Post Print Electronic structure and chemical bonding in Ti2AlC

... 共320 GPa兲.9 The change of elastic properties with crystal structure is mainly related to the fact that the 211 structure contains a smaller part of the strong Ti-C bonds and thus generally exhibits more metalliclike attributes and softness compared to the 312 and 413 structures, which exhibit more c ...
Outline - Concordia University
Outline - Concordia University

... • Soft and relatively easy to deform γ -austenite - solid solution of C in …….. Fe • The maximum solubility of C is 2.14 wt % at 1147°C. • Interstitial lattice positions are much larger than ferrite (higher C%) • Is not stable below the eutectic temperature (727 °C) unless cooled rapidly (Chapter 10 ...
V-shaped oxydiphthalimides: side-chain engineering - IISER
V-shaped oxydiphthalimides: side-chain engineering - IISER

... of light emitting diodes (OLEDs),1 solid state lasers,2 sensors,3 labels4 and thin film transistors (OTFT).5 The development of efficient solid state emitters from organic fluorophores is a challenging yet desirable task in optoelectronics. In most cases, organic dyes with high fluorescence quantum ...
Chemical Equilibrium
Chemical Equilibrium

... Changing the volume of a reactant container changes the concentration of gaseous reactants and therefore their partial pressures Equilibrium position will therefore move The value of Kc or Kp does NOT change Changing pressure by adding more of an inert gas has no effect of the equilibrium position - ...
FELDSPARS, EXSOLUTION, ZONING, and TWINNING
FELDSPARS, EXSOLUTION, ZONING, and TWINNING

... alkali feldspars are mainly potassium feldspar and albite. Albite and K-spar exhibit very limited solid solution at room temperature. If Na and K are both present in magma, the initial mineral will be a mixture of sodium and potassium but the resulting mineral will undergo exsolution as it cools. Tw ...
AP Chemistry: Chapter 13 Gaseous Equilibrium Section 1: Multiple
AP Chemistry: Chapter 13 Gaseous Equilibrium Section 1: Multiple

... A rigid container holds a mixture of graphite pellets (C(s)), H2O(g), CO(g), and H2(g) at equilibrium. State whether the number of moles of CO(g) in the container will increase, decrease, or remain the same after each of the following disturbances is applied to the original mixture. For each case, a ...
The role of chain length and conformation in stress
The role of chain length and conformation in stress

... of the order of 0.4 to 3 Jm−2 [5]). It may be mentioned that a rather weak dependence of chain length is also obtained for the elastic and anelastic properties of glassy polymers, which are cohesive in nature. A much stronger effect of chain length is found, however, under experimental conditions, w ...
Dangerous Goods - `OnGuard®` Safety Training
Dangerous Goods - `OnGuard®` Safety Training

... prevent contact with in flowing liquids such as rain. Appropriate spillage clean-up and personal protective equipment should be provided and kept in good order. The type of clean-up and personal protective equipment required, willdepend on the quantities of DG, their types and handling methods. The ...
Applications of Silicon Carbide for High Temperature Electronics and Sensors
Applications of Silicon Carbide for High Temperature Electronics and Sensors

... applications. SiC is proving to be a promising semiconductor material for such potential applications at high temperatures. SiC is one of the most refractory materials known, and thin membranes of SiC should be very robust while not rigid. And because SiC is a semiconductor material, integration of ...
Design of Filled One Step Chip Attach Materials for
Design of Filled One Step Chip Attach Materials for

... The first effect to be discussed is the response of viscosity to filler loading because if the viscosity of the filled material at high shear rates is too high then the OSCA-R material will not flow sufficiently during die placement. For the discussion of filled and formulated systems it is useful t ...
Entropy geometric construction of a pure substance with normal
Entropy geometric construction of a pure substance with normal

... shall see, the fundamental relation indicates features that are absent in usual phase diagrams, such as p−T diagrams with p pressure and T temperature. These features allows us to pose restrictions both in theoretical models as well as in measurable quantities. Furthermore, the fundamental relation ...
Novel high-temperature and pressure-compatible ultrasonic levitator
Novel high-temperature and pressure-compatible ultrasonic levitator

... pressure and the counteracting gravitational force, solid or liquid samples are levitated slightly below the pressure minima of the ultrasonic standing wave. The acoustic radiation pressure is much larger for the present standing wave produced within a resonant cavity than for a traveling wave. The ...
Mechanistic Studies on the Galvanic Replacement Reaction
Mechanistic Studies on the Galvanic Replacement Reaction

... via a chemical reduction process.18 Together with a number of studies that have also demonstrated formation of metal shells on dielectric colloidal spheres, it has been established that there was a significant red-shift for the SPR peaks relative to their solid counterparts.19,20 By selectively remo ...
The Luminescent Properties of Yttrium Oxyapatite Doped
The Luminescent Properties of Yttrium Oxyapatite Doped

... powder after thermal treatment at 800 °C. Pretty narrow diffraction peaks pointed out on a well crystallized grains and low density of strains inside crystal structure. As Ca2Y8(SiO4)6O2 is isostructural with natural oxyapatite phase Ca10(PO4)6F2, all reflections were indexed in the space group (S.G ...
Equilibrium 5
Equilibrium 5

... Consider an experiment in which gaseous N2O4 was placed in a flask and allowed to reach equilibrium at a temperature where K = 0.133 . At equilibrium, the pressure of N2O4 was found to be 2.71 atm. Calculate the equilibrium pressure of NO2 (g). ...
Physical Properties of the NbC Carbide
Physical Properties of the NbC Carbide

... transition metal carbides was extensively studied in [38] and in several other papers [39–42]. It is firmly established in the literature that the main characteristic of the chemical bonding in transition metal carbides is a covalent bonding with hybridization of the 2p orbitals of the carbon atoms ...
Lecture 3.
Lecture 3.

... o Operation: The detector is filled by natural gas. Free electrons moving by high electric field can excite the gas molecules. o If the electric field is big enough, then the electrons can absorb energy during two elastic collisions. The energy is equal to the ionization potential of the gas. During ...
Paper - Dan Johnston`s E
Paper - Dan Johnston`s E

... example being either hydrogen or Natural gas powered cars, how can we store enough gas on board to travel a given distance? One possible solution would be by using MOFs that have been designed to maximize the storage capacity of a given container of gas. This sounds counter intuitive that by placing ...
template - Communications in Inorganic Synthesis
template - Communications in Inorganic Synthesis

... The X-ray diffraction data were collected at 293(2) K with an Agilent SuperNOVA diffractometer with micro-focus X-ray using Mo radiation (λ = 0.71073 Å). CrysAlisPro [6] software was used to collect, index, scale and apply analytical absorption corrections based on faces of the crystal. The structur ...
Introduction to Alloy Phase Diagrams
Introduction to Alloy Phase Diagrams

... illustrated in Fig. 7, have fairly wide ranges of homogeneity. However, many others have very limited or no significant homogeneity range. When an intermediate phase of limited (or no) homogeneity range is located at or near a specific ratio of component elements that reflects the normal positioning ...
Synthesis and characterization of pure and doped ZnO
Synthesis and characterization of pure and doped ZnO

... chemical sensors, spintronic devices etc. [2-7], due to their unusual electrical, optical, mechanical and magnetic properties, which results from quantum confinement effects. In order to better understand these properties of pure and doped nanoparticles of ZnO, the choice of sample preparation metho ...
Material Equilibrium
Material Equilibrium

... Energy wants to shrink. Together, they make a compromise. ...
Crystallographic preferred orientations may develop in
Crystallographic preferred orientations may develop in

... experimentally deformed by diffusion-dominant processes [e.g., Sundberg and Cooper, 2008], or due to oriented growth in a strain field [e.g., Shelly, 1971]. Nevertheless, the simple observation that most tectonites with strong CPOs also have microstructures typical of dislocation creep (e.g., stretch ...
thin film opal photonic crystals - Elpub Wuppertal
thin film opal photonic crystals - Elpub Wuppertal

... PhCs are of great interest for both fundamental and applied research. Since they were first proposed in 1972 by V. P. Bykov [1] and then further in the late 1980s by E. Yablonovitch and S. John [2, 3] PhCs have gained increasing interest. PhCs are periodic dielectric structures that are designed to ...
Materials Chemistry Prof. S. Sunder Manoharan Department of
Materials Chemistry Prof. S. Sunder Manoharan Department of

... When we come to solid state materials chemistry, we are mainly concerned about few issues number 1, as I pointed put in the inaugural lecture synthesis of solids plays a very important role. And if we need to have an idea of the synthetic strategy, the most of fundamental understanding that we requi ...
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Colloidal crystal



A colloidal crystal is an ordered array of colloid particles, analogous to a standard crystal whose repeating subunits are atoms or molecules. A natural example of this phenomenon can be found in the gem opal, where spheres of silica assume a close-packed locally periodic structure under moderate compression. Bulk properties of a colloidal crystal depend on composition, particle size, packing arrangement, and degree of regularity. Applications include photonics, materials processing, and the study of self-assembly and phase transitions.
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