Download 1 - BARVY A LAKY TELURIA, sro

Survey
yes no Was this document useful for you?
   Thank you for your participation!

* Your assessment is very important for improving the work of artificial intelligence, which forms the content of this project

Transcript
PRODUCT SAFETY DATA SHEET
in accordance with Regulation 1907/2006/EC
Date of issue: 20.4.2010
Revised: 20.8.2012
Revision No.: 1
Page 1/ 8
Name of product: TELHARD PUR HARDENER FOR TWO-COMPONENT POLYURETHANE PAINTS TELPUR
1. IDENTIFICATION OF THE MIXTURE AND OF THE COMPANY:
1.1. Product identifier: TELHARD PUR HARDENER FOR TWO-COMPONENT POLYURETHANE PAINTS TELPUR
1.2. Relevant identified uses of the mixture and uses advised against: hardener for two-component polyurethane paints
Use advised against: N/A
1.3. Details of the supplier of the Safety Data Sheet:
Manufacturer: BARVY A LAKY TELURIA, s.r.o., ID No.: 43420371
Address: Skrchov 1, 679 61 Letovice, Czech Republic
Tel: +420 516 474 211 - available during working hours from 7.00 to 15.00
Fax: +420 516 474 257, Email: [email protected], [email protected], Http: www.teluria.cz
1.4. Emergency Telephone Number:
Poison Centre Na Bojišti 1, 128 08 Praha 2
Tel.: +420 224 919 293 or +420 224 915 402 - available 24h/day
2. HAZARD IDENTIFICATION:
2.1. Classification of mixture:
The mixture is classified as dangerous within the meaning of Regulation (EC) No.1272/2008 and Directive 67/548/EEC.
2.1a) Classification according to Regulation (EC) No.1272/2008
Flammable liquid: Flam. Liq. 3
Acute toxicity: Acute Tox. 4
Skin corrosion/irritation: Skin Irrit. 2
Skin sensitization: Skin Sens.1
The most serious adverse effects in terms of physical-chemical properties and effects on human health and
environment:
Flammable liquid and vapour
Harmful if inhaled
Harmful in contact with skin
Causes skin irritation
May cause an allergic skin reaction
b) Classification according to Directive 67/548/EEC
Flammable. Harmful. Irritating.
The most serious adverse effects on human health upon application: Harmful by inhalation and in contact with skin. May
cause sensitisation by skin contact.
The most serious adverse effects on the environment upon application: emision to the air
Xn: R10, R20/21, R43
Note: See Section 16 for full text of R (Risk) phrases and H (Hazard) statements.
2.2. Label elements
Signal word: warning
Hazard pictograms:
Standard hazard statements (H-phrases)
H226
Flammable liquid and vapour.
H312
Harmful in contact with skin
H315
Causes skin irritation.
H317
May cause an allergic skin reaction.
H332
Harmful if inhaled
Supplemental information
EUH204
Contains isocyanates. May produce an allergic reaction.
PRODUCT SAFETY DATA SHEET
in accordance with Regulation 1907/2006/EC
Date of issue: 20.4.2010
Revised: 20.8.2012
Revision No.: 1
Page 2/ 8
Name of product: TELHARD PUR HARDENER FOR TWO-COMPONENT POLYURETHANE PAINTS TELPUR
Prevention precautionary statements (P-phrases)
P210
Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P260
Do not breatthe vapours.
P280
Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352
IF ON SKIN: Wash with plenty of soap and water
P304+P340
IF INHALED: Remove the victim to fresh air and rest in a position comfortable for breathing.
P312
Call a POISON CENTER or doctor/physician if you feel unwell.
Hazardous components which must be listed on the label:
Xylene, mixture of isomers, hexamethylene diisocyanate, oligomers, 2-methoxy-1- methylethyl-acetate.
2.3 Other hazards:
Neither the mixture nor its components are classified as PBT (Persistent, Bioaccumulative and Toxic) or vPvB (Very Persistent
and Very Bioaccumulative) as of the date of publication of this Safety Data Sheet. Substances are neither listed in Annex XIV of
REACH nor on the REACH candidate list.
Vapours may form explosive mixture with air.
Vapours have intoxicating and narcotic effect if swallowed, inhaled and in contact with mucous membranes.
3. COMPOSITION / INFORMATION ON INGREDIENTS:
3.1. Composition: Xylene, mixture of isomers, hexamethylene diisocyanate, oligomers, 2-methoxy-1- methylethyl-acetate.
Solution of polyisocyanate in organic solvents.
3.2a) Classification of hazardous substances according to Regulation (EC) No. 1272/2008/ES (CLP Regulation)
Hazardous
Content
EC-No.
Index No.
Reg. No.
Classification,
HSignal
substance
in %
category
phrases word
**)
01-2119555267Flam. Liq. 3
H226
Xylene (mixture
12,5
215-535-7
601-022-00-9 33-XXX
Acute Tox. 4
H312
of isomers + ethyl
H332
benzene)
Skin Irrit. 2
H315
01-21194757912-methoxy-112,5
203-603-9
607-195-00-7 29-XXXX
Flam. Liq.3
H226
methylethylacetate
hexamethylene
cca 75
diisocyanate,
500-060-2
Skin Sens.1
H317
oligomers
Resp.
< 0.5
212-485-8
615-011-00-1 01-2119457571Acute Tox. 4
H302
Sens.1
hexamethylene
37-0000
(oral)
H334 c
diisocyanate
Acute Tox. 1
H330
≥ 0,5 %
(Inhalation - mist)
Acute Tox. 3
Skin
(dermal)
H311
Sens.1
Eye Irrit. 2
H317: c
STOT SE 3
H319
≥ 0,5 %
Skin Irrit. 2
H335
Resp. Sens. 1
H315
Skin Sens. 1
H334
H317
*) For full text of H-phrases see Section 16 of the Safety Data Sheet
Hazard
pictogram
GHS02
GHS07
Warning
GHS02
Warning
GHS07
Warning
GHS06
GHS08
Danger
3.2 b) Classification of hazardous substances according to Directive 67/548/EEC
Hazardous
substance
Content
in %
Reg. No.
EC-No.
CAS-No.
Xylene (mixture of
isomers + ethyl
benzene)
12,5
01-2119555267-33XXXX
215-535-7
1330-20-7
R 10
Xn R 20/21
Xi R 38
12,5
01-2119475791-29XXXX
203-603-9
108-65-6
R 10
500-060-2
28182-81-2
Xi R 43
2-methoxy-1methylethyl-acetate
hexamethylene
diisocyanate,
oligomers
cca 75
Symbols
and Rphrases **)
Concentration limits
R 20/21-38 c ≥ 20%
R 20/21,
12,5% ≤ c < 20%
c≥1
PRODUCT SAFETY DATA SHEET
in accordance with Regulation 1907/2006/EC
Date of issue: 20.4.2010
Revised: 20.8.2012
Revision No.: 1
Page 3/ 8
Name of product: TELHARD PUR HARDENER FOR TWO-COMPONENT POLYURETHANE PAINTS TELPUR
hexamethylene
diisocyanate
< 0.5
01-2119457571-370000
212-485-8
822-06-0
T R 23
R 42/43
Xi R 36/37/38
T,R 23, R 42/43:c ≥ 2%,
Xn ,R20, R 42/43: 0,5 % ≤
c<2%
T,R23, R36/37/38,
R42/43: c ≥ 20%
*) For full text of R-phrases see Section 16 of the Safety Data Sheet
4 FIRST AID MEASURES:
4.1. Description of first aid measures:
General: in all cases of doubt, or when symptoms persist, and upon accidental ingestion or eye contact, contact a physician and
give him/her information from this Safety Data Sheet.
After inhalation: remove to fresh air, keep person at rest, and prevent hypothermia (overcooling).
After skin contact: remove contaminated clothing and wash skin thoroughly with soap and plenty of water.
After ingestion: flush mouth with water and drink at least half litre of water, do not induce vomiting
After eye contact: irrigate copiously with clean water for 10 - 15 minutes, holding the eyelids wide open at all time.
4.2. Most important symptoms and effects, both acute and delayed:
The vapours have toxic and narcotic effects. The inhalation of vapours may cause drowsiness or dizziness.
When airway hypersensitivity and skin (asthma, chronic bronchitis, chronic skin disease) is not recommended contact with the
product.
4.3. Indication of any immediate medical attention and special treatment needed:
Not specified, no immediate medical help required.
5. FIRE FIGHTING MEASURES:
5.1. Appropriate extinguishing media: dry chemical powder, carbon dioxide (CO2), foam (light, medium, and heavy).
Inappropriate extinguishing media: water.
5.2. Special hazards arising from the mixture: toxic products and radiant heat may develop during fire.
5.3. Advice for fire fighters: protective clothing against radiant heat, breathing apparatuses. Cool closed containers exposed to
fire with water. Avoid leakage of spent extinguishing media into water sources; prevent it from reaching the sewage system.
6. ACCIDENTAL RELEASE MEASURES:
6.1. Personal precautions, protective equipment and emergency procedures: Avoid breathing vapours and skin and eye
contact. Use proper protective clothes and gloves, as well as protective goggles, face shield and proper respiratory protection
equipment, if necessary. Arrange inflow of fresh air in closed rooms. Eliminate all possible sources of ignition. No smoking or
open flames.
6.2. Environmental precautions: avoid release to the environment; don’t let the leakage reach sewage system – danger of
explosion.
6.3. Methods and materials for containment and cleaning up: collect mechanically, with residues to be absorbed with
suitable absorbents /vermiculite, sand, earth, sawdust/ and place in proper container for disposal. Clean up the contaminated
land.
6.4. Reference to other sections: see Sections 8 and 13.
7. HANDLING AND STORAGE:
7.1. Precautions for safe handling: Avoid breathing vapours and skin and eye contact. Use proper protective clothes and
gloves, as well as protective goggles and face shield. Vapours of volatile fractions form an explosive mixture with air. Use only in
well-ventilated areas with ensured inflow of fresh air. Observe all fire safety measures (no smoking or open flames, eliminate all
possible sources of ignition). Do not eat, drink or smoke while working.
Caution: Do not wear contact lenses while working with preparations containing organic solvents.
7.2. Conditions for safe storage, including any incompatibilities:
Store in closed containers, in ventilated areas at 5 – 25°C according to ČSN 65 0201 standard. The storage area must be
equipped with first aid equipment and drinking water supply
Keep away from food, drinks, animal feedstuffs and ignition sources (open flames, sparks, and hot surfaces).
7.3. Specific end uses: not specified
8. EXPOSURE CONTROLS AND PERSONAL PROTECTION:
8.1. Control parameters:
The product contains substances having following permissible occupational exposure limits (OELs) and maximum
permissible concentrations (MPCs) in working environment (Government Regulation No. 361/2007 Coll.)
CAS-No.
Substance
OEL [mg.m-3]
MPC [mg.m-3]
Note
108-65-6
2-methoxy-1270
550
D
methylethyl-acetate
1330-20-7
xylene
200
400
D
100-41.4
etylbenzen
200
500
D
822-06-0
Hexametylene
0,035
0,07
diisokyanate
Note: D: the substance rapidly penetrates or irritates the skin upon exposure.
Limit values of indices from biological exposure tests in urine (Decree No. 432/2003)
Substance
Indicator
Limit values
Xylenes
methylhippuric acid
1400 mg/g creatinine
Time of sample collection
at the end of workday
PRODUCT SAFETY DATA SHEET
in accordance with Regulation 1907/2006/EC
Date of issue: 20.4.2010
Revised: 20.8.2012
Revision No.: 1
Page 4/ 8
Name of product: TELHARD PUR HARDENER FOR TWO-COMPONENT POLYURETHANE PAINTS TELPUR
820 µmol/mmol creatinine
1500 mg/g creatinine
1100 µmol/mmol creatinine
Ethylbenzene
at the end of workday
DNEL and PNEC values taken from the material safety data sheets:
Note: The Derived No Effect Level (DNEL) is an estimated safe level of exposure that is derived from toxicity data in accord with
specific guidance within the European REACH regulation. The DNEL may differ from an Occupational Exposure Limit (OEL) for
the same chemical. OELs may be recommended by an individual company, a governmental regulatory body or an expert
organization, such as the Scientific Committee for Occupational Exposure Limits (SCOEL) or the American Conference of
Governmental Industrial Hygienists (ACGIH). OELs are considered to be safe exposure levels for a typical worker in an
occupational setting for an 8-hour work shift, 40 hour work week, as a time weighted average (TWA) or a 15 minute short-term
exposure limit (STEL). While also considered to be protective of health, OELs are derived by a process different from that of
REACH.
1) 2-methoxy-1- methylethyl-acetát:
The Derived No-Effect Level (DNEL)
Workers
Possible health effects
Acute – systemic effects
Acute – systemic effects
Acute – systemic effects
Acute – local effects
Acute – local effects
Long-lasting - systemic effects
Long-lasting - systemic effects
Long-lasting - systemic effects
Long-lasting - local effects
Long-lasting - local effects
Possible ways of exposure
contact with skin
inhalation
ingestion
contact with skin
inhalation
contact with skin
inhalation
ingestion
contact with skin
inhalation
Value
unavailable
unavailable
unavailable
unavailable
unavailable
54.8mg/kg body weight per day
33mg/m3
1.67mg/kg body weight per day
unavailable
unavailable
Consumers
Possible health effects
Acute – systemic effects
Acute – systemic effects
Acute – local effects
Acute – local effects
Long-lasting - systemic effects
Long-lasting - systemic effects
Long-lasting - local effects
Long-lasting - local effects
Possible ways of exposure
contact with skin
inhalation
contact with skin
inhalation
contact with skin
inhalation
contact with skin
inhalation
Value
unavailable
unavailable
unavailable
unavailable
153.5mg/kg body weight per day
275mg/m3
unavailable
unavailable
Predicted No-Effect Concentration (PNEC)
Environmental compartment
Fresh water
Marine water
Intermittent release
Sewage treatment plant
Fresh water sediment
Marine sediment
Soil
Value
0.635 mg/l
0.0635 mg/l
6.35 mg/l
100 mg/l
3.29 mg/kg d.w.
0.329 mg/kg d.w.
0.29 mg/kg d.w.
2) Hexamethylene-1,6-diisocyanate
DNEL (The Derived No-Effect Level):
Workers (short-term exposure):
DNEL dermal – systemic effects:
Risks cannot be quantified. The most sensitive endpoint: sensitisation (respiratory tract)
DNEL inhalation – systemic effects: 0.07 mg/m³ air
The most sensitive endpoint: irritation (respiratory tract)
Workers (long-term exposure):
DNEL dermal – systemic effects:
Risks cannot be quantified. The most sensitive endpoint: sensitisation (respiratory tract)
DNEL inhalation – systemic effects: 0.035 mg/m³ air
The most sensitive endpoint: irritation (respiratory tract)
PRODUCT SAFETY DATA SHEET
in accordance with Regulation 1907/2006/EC
Date of issue: 20.4.2010
Revised: 20.8.2012
Revision No.: 1
Page 5/ 8
Name of product: TELHARD PUR HARDENER FOR TWO-COMPONENT POLYURETHANE PAINTS TELPUR
DNEL dermal – local effects:
Risks cannot be quantified. The most sensitive endpoint: sensitisation (respiratory tract)
DNEL inhalation – local effects: 0.035 mg/m³ air
The most sensitive endpoint: irritation (respiratory tract)
PNEC (Predicted No-Effect Concentration):
Fresh water: > 0.0774 mg/L
Marine water: > 0.00774 mg/L
Freshwater sediment: > 0.01334 mg/kg (dry weight)
Marine water sediment: > 0.001334 mg/kg (dry weight)
Soil: > 0.0026 mg/kg (dry weight)
Wastewater treatment plant: 8.42 mg/L
Oral:
N/A
8.2. Exposure controls:
General safety and hygiene measures: Never eat, drink or smoke while working. Wash hands with warm, soapy water before
breaks and at the end of the workday; apply regeneration cream
Effective general ventilation and local exhaust ventilation.
8.2.1. Personal protection, including personal protection equipment:
Eye and face protection: Organic solvent resistant closed safety glasses or face shield.
Skin protection: Anti-static work clothing.
Hand protection: Organic solvent resistant gloves.
Respiratory protection: If exposed to concentrations above OEL, half-mask respirator with organic aerosol filter is necessary.
8.2.2. Environmental controls
Observe safe handling and storage measures. Do not discharge into sewage system, water flows or soil.
9. PHYSICAL AND CHEMICAL PROPERTIES:
9.1. Information on basic physical and chemical properties:
Appearance and physical state: liquid
Colour: yellowish
Odour: typical aromatic
Odour threshold: no data available
pH (20°C): no data available
Freezing point (°C): no data available
Boiling point/boiling range (°C):
xylenes: 136-143
2-methoxy-1- methylethyl-acetate: 145,8
Flash point (°C): min 25 (mixture)
xylenes: 24-29
2-methoxy-1- methylethyl-acetate: 45,5
Evaporation rate: not specified for coating compositions
Flammability: flammable liquid
Self-ignition temperature (°C):
xylenes: 494
2-methoxy-1- methylethyl-acetate: 333
Vapour pressure: no data available
Vapour density: no data available
Explosive properties: Explosive limits: xylenes: upper limit (% b.v.): 6-8
2-methoxy-1- methylethyl-acetate: upper limit (% b.v.):7
Hexametylene diisokyanate: upper limit (% b.v.): 9,5
lower limit (% b.v.): 1-2
lower limit (% b.v.): 1,5
lower limit (% b.v.):: 0,9
Product density (g/cm3): 1,07
Solubility in water: insoluble
Oxidizing properties: shows no oxidizing properties
Partition coefficient n-octanol/water: no data available
Viscosity kinematic (40°C) (mm2/s) > 20.5
9.2. Other information:
Hazard class: II
10. STABILITY AND REACTIVITY:
10.1. Reactivity: No dangerous reactions are known under conditions of normal use.
10.2. Chemical stability: The product is volatile and evaporates even at normal temperature and pressure. It is stable when
stored and handled under normal conditions of surrounding environment.
10.3. Possibility of hazardous reactions: Vapours of volatile fractions form an explosive mixture with air.
10.4. Conditions to avoid: Intensive heating, concentrations within the explosive limits.
PRODUCT SAFETY DATA SHEET
in accordance with Regulation 1907/2006/EC
Date of issue: 20.4.2010
Revised: 20.8.2012
Revision No.: 1
Page 6/ 8
Name of product: TELHARD PUR HARDENER FOR TWO-COMPONENT POLYURETHANE PAINTS TELPUR
10.5. Incompatible materials: Exothermic reaction with amines and alcohols. Due to reaction with water there is a gradual
development of CO2, in a closed tin growth pressure bursting.
10.6. Hazardous decomposition products: burning may produce toxic products and fumes, carbon monoxide, nitrogen oxide,
isocyanate vapor, traces of hydrogen cyanide.
11. TOXICOLOGICAL INFORMATION:
11.1.1. Information on toxicological effects:
Acute toxicity:
Harmful by inhalation and in contact with skin
Substance
CAS- No.
LD50 oral, rat
LC50 inhalation, rat
LD50 dermal, rabbit
xylene
2-methoxy-1- methylethyl-acetate
Hexametylene diisokyanate,
oligomers
Hexametylene diisokyanate
1330-20-7
108-65-6
28182-81-2
4300 mg/kg
> 5000 mg/kg
> 5000 mg/kg
4500 mg/kg
> 5000 mg/kg
údaje nejsou k dispozici
822-06-0
746 mg/kg
6350 mg/m3/4h
>4500ppm/6h
údaje nejsou k
dispozici
124 mg/m3/4h
> 7000 mg/kg
Note: Data were taken from the raw material suppliers´ safety data sheets, Industrial Toxicology (by Marhold).
Skin corrosion/irritation: Irritates skin.
Serious eye damage/irritation: Available data do not meet the criteria for classification.
Respiratory/skin sensitisation: The product contains isocyanates that may cause sensitisation by skin contact.
Carcinogenicity: Available data do not meet the criteria for classification.
Mutagenicity: Available data do not meet the criteria for classification.
Reproductive toxicity: Available data do not meet the criteria for classification.
Specific target organ toxicity/single exposure: Available data do not meet the criteria for classification.
Specific target organ toxicity/repeated exposure: Available data do not meet the criteria for classification.
Aspiration: Available data do not meet the criteria for classification.
12. ECOLOGICAL INFORMATION:
12.1. Ecotoxicity:
No danger of aquatic ecotoxicity is expected:
Data are given for individual substances:
Substance
CAS-No.
xylene
2-methoxy-1- methylethyl-acetate
Hexametylene diisokyanate,
oligomers
Hexametylene diisokyanate
LC50 fish/96 h
EC50 daphnia/48 h
IC50 algae/72 h
1330-20-7
108-65-6
28182-81-2
86 mg/l
100-180 mg/l
>100 mg/l
165 mg/l
408-500 mg/l
>100 mg/l
160 mg/l
>1000 mg/l
>100 mg/l
822-06-0
>83 mg/l
>89 mg/l
>77 mg/l
12.2. Persistence and degradability: xylene 2-methoxy-1- methylethyl-acetate - substances are easily biodegradable.
Hexametylene diisokyanate, oligomers, hexametylene diisokyanate - substances are not easily biodegradable.
12.3. Bio-accumulative potential: bio-accumulative potential of substances is low.
12.4. Mobility in soil: The product is a low-viscosity liquid. In case of leakage into environment, it may be dispersed over large
distances and penetrate into underground water.
12.5 Results of PBT and vPvB assessments: The product does not meet criteria for classification into PBT or vPvB
substances.
12.6 Other adverse effects: The product in contact with the water is transformed into insoluble product (polyurea) and carbon
dioxide is developed. This reaction is accelerated by surfactants, such as liquid soaps or water-soluble solvents.
Dangerous for drinking water supplies. Prevent penetration into the ground water, drinking water, soil and drainage.
13. DISPOSAL CONSIDERATIONS:
Product residues, contaminated materials and empty disposable contaminated packaging must be disposed of by waste
producer according to Act No. 185/2001 Coll. on waste and on amendment to some other acts, and Act No. 477/2001 Coll. on
packaging and on amendment to some other acts.
When properly emptied, deliver the used package to a package waste collection centre. Packages retaining product residues
should be delivered to a hazardous waste disposal place designed by a municipality or handed over to a person authorised to
dispose of hazardous waste.
13.1. Regulatory disposal information:
Waste code:
Waste paint and varnish containing organic solvents or other hazardous substances: 08 01 11
Packaging containing residues of or contaminated by hazardous substances: 15 01 10
The component rendering waste hazardous according to Annex 5 to Act No.185/2001 Coll.: C 41 organic solvents, with the
exception of halogenated solvents.
14. TRANSPORT INFORMATION:
PRODUCT SAFETY DATA SHEET
in accordance with Regulation 1907/2006/EC
Date of issue: 20.4.2010
Revised: 20.8.2012
Revision No.: 1
Page 7/ 8
Name of product: TELHARD PUR HARDENER FOR TWO-COMPONENT POLYURETHANE PAINTS TELPUR
14.1 Special precautions – Guidance in case of accident is necessary
14.2 Hazardous classification of dangerous goods for individual types of transport
Land transport ADR/RID:
Hazard Identification No:
30
Transport hazard class: 3
Proper shipping name: RESIN SOLUTION, flammable
UN No.:
1866
Inland Waterways AND/ADNR:
Hazard Identification No:
30
Label:
3
Transport hazard class: 3
Proper shipping name:RESIN SOLUTION, flammable
UN No.:
Air transport ICAO/IATA
Hazard Identification No:
1866
Label:
Packing Group: III Classification-Code:
30
Transport hazard class: 3
Proper shipping name: RESIN SOLUTION, flammable
UN No.:
1866
Page:
Packing Group: III PAX:
3
Packing Group: III Classification-Code:
309 CAO:
F1
F1
310
14.3. Environmental hazards: no
14.4. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: not classified
15. REGULATORY INFORMATION:
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Regulation (EC) No 1907/2006 of the European Parliament and of the Council concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, as well as related
implementing regulations
Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of
substances and mixtures, as amended
Act No. 350/2011 Coll. on chemical substances and chemical mixtures, as amended , Decree No. 402/2011 Coll. on evaluation
of dangerous properties of chemical substances and chemical mixtures and packaging and labelling of dangerous chemical
mixtures ▪ Act No.185/2001 Coll. on Waste and on amendment to some other acts, Decree No. 381/2001 Coll., the Catalogue
of Waste ▪ Decree No. 383/2001 Coll. on details of waste treatment ▪ Act No. 258/2000 Coll. on Public Health Protection ▪ Order
of the Government No. 178/2001 Coll. laying down the conditions for employee health protection at work ▪ Decree No. 432/2003
Coll. laying down the conditions for assigning categories to individual jobs, limit values of indices from biological exposure tests,
and the particulars of the reports on work with asbestos and biological agents ▪ Act No. 86/2002 Coll., the Clean Air Act ▪
Decree No. 337/2010 Coll., on emission limits and other conditions for operation of other stationary sources of air pollution that
emit and utilize volatile organic compounds and on handling of products containing volatile organic compounds ▪ Act No.
477/2001 Coll. on packages as amended ▪ Decree No. 115/2002 Coll. laying down the details of package handling. ▪ Act
No. 59/2006 Coll. on the Prevention of Major Industrial Accidents. ▪ Common Position (EC) No.33/2005 Coll. (ADR), Common
Position (EC) No. 34/2005 Coll. (RID)
15.2. Chemical safety assessment:
A Chemical Safety Assessment has been carried out for the substances 2-methoxy-1- methylethyl-acetate.
No report on chemical safety for pother substances was provided by the supplier until the publication of this Safety Data Sheet.
16. OTHER INFORMATION:
16a) Changes made in the Safety Data Sheet within the revision process:
Version
1
1st revision
Date
20.4.2010
28.11.2010
Changes
Complete revision of all sections of the Safety Data
Sheet according to the Regulation (EC) of the
European Parliament and of the Council
No. 453/2010 and Regulation (EC) of the European
Parliament and of the Council No. 1272/2008
16b) Key or legend to abbreviations:
Flammable liquid, category 3: Flam. Liq. 3
Acute toxicity, category 4: Acute Tox. 4
Skin corrosion/irritation, category 2: Skin Irrit. 2
Respiratory/skin sensitisation, category 1: Skin Sens.1
EINECS
European Inventory of Existing Commercial Chemical Substances
ELINCS
European list of notified chemical substances
16c) Most important information sources used to compile this Safety Data Sheet:
PRODUCT SAFETY DATA SHEET
in accordance with Regulation 1907/2006/EC
Date of issue: 20.4.2010
Revised: 20.8.2012
Revision No.: 1
Page 8/ 8
Name of product: TELHARD PUR HARDENER FOR TWO-COMPONENT POLYURETHANE PAINTS TELPUR
Raw material suppliers´ safety data sheets, database of ECB ESIS : EINECS/ELINCS (European Chemicals Bureau –
European Chemical Substances Information System) ChemDat Merck, Fluka, Fire and safety technical characteristic values of
hazardous substances
16d) List and full text of applied risk phrases, standard hazard statements and prevention precautionary statements:
R10
Flammable
R 20/21
Harmful by inhalation and in contact with skin
R 43
May cause sensitisation by skin contact
H226
H312
H315
H317
H332
EUH204
Flammable liquid and vapour
Harmful in contact with skin
Causes skin irritation
May cause an allergic skin reaction
Harmful if inhaled
Contains isocyanates. May produce an allergic reaction.
P210
P260
P280
P302+P352
P304+P340
P312
Keep away from heat/sparks/open flames/hot surfaces – No smoking.
Do not breatthe vapours.
Wear protective gloves/protective clothing/eye protection/face protection.
IF ON SKIN: Wash with plenty of soap and water
IF INHALED: Remove the victim to fresh air and rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
16e) Instructions for training:
Any legal person and/or individual entrepreneur handling this chemical product must become familiar with data contained in this
Safety Data Sheet and receive training on safety rules
16f) Additional information:
Values for setting emission limits:
The product is only intended for use in plants or for activities regulated under Act No. 86/2002 Coll., the Clean Air Act and
Decree No. 337/2010 Coll., as amended.
Density of hardened mixture in g/cm3
Organic solvent content /VOC/ in kg per kg hardened mixture
Total organic carbon /TOC/ content in kg per kg hardened mixture
1.07
0.25
0.17
This Safety Data Sheet was compiled in accordance with Regulation (EC) No. 1907/2006 of the European Parliament and of the
Council, as amended, and Regulation (EC) of the European Parliament and of the Council No. 453/2010. It contains all
necessary data concerning job safety and health protection and environmental protection. The above-mentioned data
correspond to our present state of knowledge and experience and comply with applicable legal regulations. They cannot be
considered as a guarantee of suitability and usability of a product for any specific application
16g. Contact point for providing technical information:
Tel: +420 516 474 211, Fax: +420 516 474 257, Email: [email protected], [email protected] Http: www.teluria.cz
Similar
ACROSS 1 Cuddled 5 Gem surface 12 Moors boat 16 Spoke loudly
ACROSS 1 Cuddled 5 Gem surface 12 Moors boat 16 Spoke loudly