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The Mole Concept Lesson 1 Chemical Calculations Atoms and molecules are EXTREMELY small. If they are so small and so light how are we suppose to measure and weigh them? Answer We weigh large numbers of them to get them into GRAMS/MOLE…. g/mol Avogradro took did experiments and determined how many Hydrogen atoms it would take to weigh 1.00 grams. He found that: To get 1.00 grams of hydrogen you needed: 6.02 x 1023 hydrogen atoms. He referred to this number as a mole. Avogradro’s Number Avogradro’s Number = 6.02 x 1023 1 dozen donuts is: 1 century is: 12 100 years. 1 millennium is: 1 mole is: 1000 years. 6.02 x 1023 particles/atoms/molecules The Mole Concept A mole: The weight of 6.02 x 1023 atoms of an element….a mole of different elements weighs different amounts. 1 mole of Carbon: 1 mole of Calcium: 12.0 grams 40.1 grams ***The weight of 1 mole of an element is known as its ATOMIC MASS*** A mole of a compound is an observable quantity. It can be weighed and used in experiments. LEFT: Proceeding clockwise from the top, samples containing one mole each of copper, aluminum, iron, sulfur, iodine, and (in the center) mercury. 1 mole of hockey pucks would equal the mass of the moon! 1 mole of basketballs would fill a bag the size of the earth! A. What is the Mole? 1 mole of pennies would cover the Earth 1/4 mile deep! One mole = 6.02 x 1023 atoms, molecules, or ions (Avogadro’s number) When coefficients are used to balance chemical equations, they express a mole-to-mole ratio of the products and reactants. These numbers do not represent the exact number of moles for the reactants or products, but rather give a ratio we can use to compare quantities. Molar Mass Mass of 1 mole of an element or compound. Atomic mass tells the... atomic mass units per atom (amu) grams per mole (g/mol) Round to 1 decimal places carbon 12.0 g/mol aluminum 27.0 g/mol zinc 65.4 g/mol Molar Mass Examples water H2O 2(1.0) + 16.0 = 18.0 g/mol sodium chloride NaCl 23.0 + 35.5 = 58.5 g/mol Molar Mass Examples sodium bicarbonate NaHCO3 23.0 + 1.0 + 12.0 + 3(16.0) = 84.0 g/mol sucrose C12H22O11 12(12.1) + 22(1.0) + 11(16.0) = 343.2 g/mol Molar Mass Examples molar mass 6.02 1023 NUMBER MASS MOLES IN OF PARTICLES GRAMS (g/mol) (particles/mol) Molar Conversions Example 1 Convert 2.5 x 1025 atoms of Carbon into moles. 2.5 x 1025 atoms 6.02 x 1023 atoms/mol = 42 moles Example 2 Convert 16.3 moles of Carbon dioxide (CO2) into molecules. 16.3 moles X 6.02 x 1023 molecules per mole. = 9.81 x 1024 Molecules Example 3 Convert 8.9 x 1024 molecules of Carbon dioxide (CO2) into moles. 8.9 x 1024 Molecules 6.02 x 1023 Molecules/mol = 14.78405316 moles = 15 moles X or ÷ ??? What units do you want? Example 4 (YOU TRY) Convert 28 moles of NaCl into molecules. 28 moles X 6.02 x 1023 molecules per mole. = 1.7 x 1025 Molecules Avogradro’s Hypothesis Avogradro’s Hypothesis Avogradro hypothesized that equal volumes of gas, at the same temperature and pressure contain the same number of moles. Avogradro’s Hypothesis So….. If 1 L of gas A reacts with 1L of gas B, then the formula for the compound will be: AB If 2 L of gas A reacts with 1L of gas B, then the formula for the compound will be: A2B Avogradro’s Hypothesis If 2 L of gas A reacts with 3L of gas B, then the formula for the compound will be: A2B3 Avogradro’s Hypothesis In other words, however many liters of a gas you have that are in a reaction, the amount (Liters) turns into the subscript. ***MAKE SURE ITS CONSTANT TEMP AND PRESSURE OR IT DOESN”T WORK*** You Try If 2 L of gas X contains 4 x 1023 molecules at CONSTANT TEMP AND PRESSURE, how many molecules will be present in 4 L of gas Z? Double volume means double molecules. (4 x 1023) x 2 = 8 x 1023 molecules. What’s the formula of the resulting compound? X2Z4 Work Time Questions: Pg. 78 #s: 2,3,4,5